かお
face
kao
JMdict 1217730
かお顔faceがあかい赤いredよ
が (subject) marks 顔かお (face) as the subject, and the i-adjective 赤いあかい (red) works as the whole predicate — no copula needed after an i-adjective. The casual よ (you know) flags new information, like pointing it out to the other person.